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Thermal response measurements as well as volumetric water physisorption measurements are applied to study the influence of particle sizes on water adsorption capacity and kinetics. For this, a controlled thermal condensation process followed by a mechanical treatment using a ball mill is applied to synthesize C2N-type carbon materials with smaller and larger particle sizes. The nitrogen-rich surfaces and narrow distributed micropores endow them with remarkable hydrophilic features. Using the InfraSORP technique, a fast and accurate assessment of these properties is demonstrated.
Du, S.; Leistenschneider, D.; Xiao, J.; Dellith, J.; Troschke, E.; Oschatz, M. Application of Thermal Response Measurements to Investigate Enhanced Water Adsorption Kinetics in Ball-Milled C2N-Type Materials. ChemistryOpen 2022, 11 (12), e202200193.